2-Meth­oxy-6-[(Z)-[(5-methyl-2-pyrid­yl)imino­meth­yl]phenol

نویسندگان

  • Xin-Yu Liu
  • Yu-Hua Fan
  • Cai-Feng Bi
  • Qiang Wang
  • Yuan Gao
چکیده

The title compound, C(14)H(14)N(2)O(2), was obtained by a condensation reaction between o-vanillin and 5-methyl-pyridin-2-amine. In the mol-ecule, the dihedral angle between the pyridine and benzene rings is 9.08 (13)°. An intra-molecular hydrogen bond involving the imine N atom and the hydroxyl group may influence the conformation of the mol-ecule. The crystal structure is stabilized by weak C-H⋯O hydrogen bonds.

برای دانلود رایگان متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

5-Meth­oxy-2-{[4-(morpholin-4-yl)phen­yl]imino­meth­yl}phenol

In the title compound, C(18)H(20)N(2)O(3), the dihedral angle between the two aromatic rings is 33.66 (6)°. The morpholine ring adopts a chair conformation. The mol-ecular structure is stabilized by an intra-molecular O-H⋯N hydrogen bond. In the crystal, mol-ecules are linked via weak inter-molecular C-H⋯O and C-H⋯π inter-actions.

متن کامل

(E)-2-Meth­oxy-6-[(5-methyl­isoxazol-3-yl)imino­meth­yl]phenol

In the title mol-ecule, C(12)H(12)N(2)O(3), the benzene and isoxazole rings form a dihedral angle of 5.9 (6)°. The hydr-oxy group is involved in an intra-molecular O-H⋯N hydrogen bond [O⋯N = 2.616 (5) Å], resulting in approximate planarity of the mol-ecular skeleton. In the crystal structure, mol-ecules related by translation along the c axis are stacked into columns, the shortest inter-molecul...

متن کامل

A chiral photochromic Schiff base: (R)-4-meth­oxy-2-[(1-phenyl­ethyl)imino­meth­yl]phenol

The title chiral photochromic Schiff base compound, C(16)H(17)NO(2), was synthesized from (R)-1-phenyl-ethyl-amine and 5-methoxy-salicylaldehyde. The mol-ecule of the title compound exists in the phenol-imine tautomeric form. The dihedral angle between the two aromatic rings is 62.61 (11)°. An intra-molecular O-H⋯N hydrogen bond with an O⋯N distance of 2.589 (2) Å is observed. The crystal packi...

متن کامل

3-Meth­oxy-2-[(E)-(4-meth­oxy­phen­yl)imino­meth­yl]phenol

The title compound, C(15)H(15)NO(3), adopts the enol-imine tautomeric form. The two rings are twisted with respect to each other, making a dihedral angle of 44.08 (5)°. The 3-methoxy-2-[(E)-(4-methoxyphenyl)-iminomethyl]phenol unit is almost planar, the largest deviation from the mean plane being 0.047 (2) Å. Such a planar conformation might be related to the occurrence of an intra-molecular O-...

متن کامل

Bis{(E)-2-meth­oxy-6-[(4-methyl­phen­yl)­imino­meth­yl]phenolato}zinc(II)

The title compound, [Zn(C(15)H(14)NO(2))(2)], contains a four-coordinate Zn atom located on a twofold rotation axis that exhibits a distorted tetra-hedral geometry by two phenolate O atoms and two azomethine N atoms of the Schiff base 2-methoxy-6-[(4-methyl-phen-yl)imino-meth-yl]phenolate ligands.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

عنوان ژورنال:

دوره 65  شماره 

صفحات  -

تاریخ انتشار 2009